Host Isabel Wart and refugee Olena Mykhailova waved off the convoy from Stoke Gabriel on Wednesday morning.
Wart said: “For me, it just means that Ukraine is not forgotten and I think that’s really, really important particularly as the war goes on.
“I’m just really proud of this community and what people across Devon have done and I think it’s remarkable that we’ve been continuing to be able to send aid.
“I just want to give a message to the Ukrainian people that we will be with them for however long it takes.”
Mykhailova said the village was “very kind for Ukraine”.
She said: “Every month this village and Ukraine Action help Ukraine.
“I say every day thank you, thank you so much this country, these people, this village, these amazing people.”
Follow BBC Devon on X, external, Facebook, external and Instagram, external. Send your story ideas to spotlight@bbc.co.uk, external.
